Delocalisation pins down meaning of bond order

Quantum atoms appearing in the N8 molecule.

Source: © Royal Society of Chemistry

Reliable bond order definition provides new insights into covalency

Theoretical chemists in the UK and Spain have provided a vivid demonstration of the usefulness of a quantum mechanical definition of bond order. Their new study draws attention to a foundational but neglected concept in chemistry in a way that will help provide a better understanding of unusual bonding.